Product ID:ROYAL BLUE MET, 14790D
MSDS Date:05/14/1999
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLQWR

E.I. DUPONT DE NEMOURS & CO., (INC.) AUTOMOTIVE

WILMINGTON, DE 19898
US

Emergency Phone: 800-424-9300

Info Phone: 800-441-7515/800-441-3637

Cage: UO195

E.I. DUPONT DE NEMOURS & CO., (INC.) AUTOMOTIVE

WILMINGTON, DE 19898 US

Telephone: 800-441-7515/800-441-3637

Cage: UO195

MEDIUM MINERAL SPIRITS

CAS: 64742-88-7

OSHA PEL NONE

ACGIH TLV: NONE

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 200 PPM, 300 PPM (C)

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYL BENZENE

CAS: 95-63-6

RTECS: DC3325000

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CUMENE

CAS: 98-82-8

RTECS: GR8575000

OSHA PEL 50 PPM (SKIN)

ACGIH TLV: 50 PPM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AROMATIC HYDROCARBON

CAS: 64742-95-6

RTECS: WF3400000

OSHA PEL NONE

ACGIH TLV: NONE

NAPHTHALENE

CAS: 91-20-3

RTECS: OJ0525000

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

AROMATIC HYDROCARBON

CAS: 64742-94-5

RTECS: WF3100000

OSHA PEL NONE

ACGIH TLV: NONE

ALKYD RESIN

CAS: 66070-61-9

OSHA PEL NONE

ACGIH TLV: NONE

VM&P NAPHTHA

CAS: 64742-89-8

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

LEAD NAPHTHENATE

CAS: 61790-14-5

RTECS: QK9150000

OSHA PEL 50 UG/M3 (LEAD)

ACGIH TLV: 150 UG/M3 (LEAD)

PHTHALOCYANINE BLUE PIGMENT

CAS: 147-14-8

RTECS: GL8510000

OSHA PEL 1.0 MG/M3 (CU)

ACGIH TLV: 1.0 MG/M3 (CU)

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE NOSE AND THROAT
IRRITATION. MAY CAUSE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY
THE FOLLOWING PROGRESSIVE STEPS: HEADACHE, DIZZINESS, NAUSEA,
STAGGERING GAIT, CONFUSION, UNCONSC IOUSNESS. REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. SKIN OR EYE CONTACT:
MAY CAUSE IRRITATION OR BURNING OF THE EYES. RE PEATED OR PROLONGED
LIQUID CONTACT MAY CAUSE SKIN IRRITATION WITH DISCOMFORT AND
DERMATITIS. OTHER POTENTIAL HAZARDS INCLUDE: MEDIUM MINERAL
SPIRITS: LABORATORY STUDIES WITH RATS HAVE SHOWN THAT PETR OLEUM
(SIGNS & SYMPTOMS OF OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT):
DISTILLATES CAN CAUSE KIDNEY DAMAGE AND KIDNEY AND LIVER TUMORS.
THESE EFFECTS WERE NOT SEEN IN SIMILAR STUDIES WITH GUINEA PIGS,
DOGS, OR MONKEYS. SEVERAL STU DIES EVALUATING PETROLEUM WORKERS
HAVE NOT SHOWN A SIGNIFICANT INCREASE OF KIDNEY DAMAGE OR AN
INCREASE IN KIDNEY OR LIVER TUMORS. TOLUENE: RECURRENT
OVEREXPOSURE MAY RESULT IN LIVER AND KIDNEY INJUR Y. HIGH AIRBORNE
LEVELS HAVE PRODUCED IRREGULAR HEARTBEATS IN ANIMALS AND OCCASIONAL
PALPITATIONS IN HUMANS. RATS EXPOSED TO VERY HIGH AIRBORNE LEVELS
HAVE EXHIBITED HIGH FREQUENCY HEARING DEFICITS. T HE SIGNIFICANCE
OF (TOXICOLOGICAL INFO)
Medical Cond Aggravated by Exposure:TOLUENE: INDIVIDUALS WITH
PREEXISTING DISEASES OF THE CENTRAL NERVOUS SYSTEM MAY HAVE
INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.
XYLENE: INDIVIDUALS (SUPPLEMENTAL SAFETY & HEALTH)

First Aid:INHALATION: IF AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST,
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION,
PREFERABLY MOUTH-TO-MOTH. IF BREATHING DIFFICULTY PERSISTS, OR
OCCURSL ATER, CONSULT A PHYSICIAN. SKIN OR EYE: IN CASE OF
CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES; CALL A PHYSICIAN. IN CASE OF SKIN CONTACT, WASH WITH SOAP
AND WATER. IF IRR ITATION OCCURS, CONTACT A PHYSICIAN. INGESTION:
GASTRO-INTESTINAL DISTRESS. IN THE UNLIKELY EVENT OF INGESTION,
CALL A PHYSICIAN IMMEDIATELY AND HAVE NAMES OF INGREDIENTS
AVAILABLE.

Flash Point Method:CC
Flash Point:=22.8C, 73.F
73 F TO < 100 F
Lower Limits:.8% APPROX.
Upper Limits:7.0% APPROX.
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT, INCLUDING
SELF-CONTAINED BREATHING APPARATUS (NIOSH APPROVED - ), IS
RECOMMENDED. WATER FROM FOG NOZZLES MAY BE USED TO PREVENT PRESSURE
BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASHPOINT, EMITS
FLAMMABLE VAPORS WHICH, WHEN MIXED WITH AIR, CAN BURN OR BE
EXPLOSIVE. FINE MIST OR SPRAYS MAY BE FLAMMABLE AT TEMPERATURES
BELOW THE FLASH POINT.

Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT AND BREATHING OF VAPOR. CONFINE AND REMOVE
WITH INERT ABSORBENT.

Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING. WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING. DO NOT ST ORE ABOVE 120 DEG F.
Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR DRY WELD COATING
WITHOUT A NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION.

Respiratory Protection:DO NOT BREATHE VAPORS OR MISTS. WEAR A PROPERLY
FITTED AIR PURIFYING RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES
(NIOSH APPROPVED TC-23C) AND PARTICULATE FILTER (NIOSH TC-84A)
DURING APPLICATION UNTIL AL L VAPORS AND SPRAY MISTS ARE XEHAUSTED.
FOLLOW THE RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS AND OTHER
APPLICABLE EXPOSURE LIMITS.
Protective Gloves:NEOPRENE GLOVES ARE RECOMMENDED.
Eye Protection:GOGGLES (ANSI APPROVED - ) ARE PREFERRED TO PREVENT EYE
IRRITATION.
Other Protective Equipment:PROTECTIVE CREAMS: DO NOT USE FOR
PROTECTION. MAY BE USED FOR EASE OF CLEAN UP. PROTECTIVE
CLOTHING: COVERALLS ARE RECOMMENDED. EYEWASH FOUNTAIN AND DELUGE
SHOWER MEETING ANSI DESIGN CRITERIA .
Supplemental Safety and Health
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE (CONT): WITH PRE-EXISTING
DISEASE OF THE CENTRAL NERVOUS SYSTEM, KIDNEYS, LIVER,
CARDIOVASCULAR SYSTEM, LUNGS, OR BONE MARROW MAY HAVE INCREASED
SUSCEPTIBILIT Y TO THE TOXICITY OF EXCESSIVE EXPOSURES.
NAPHTHALENE: INDIVIDUALS WITH PREEXISTING DISEASES OF THE LIVER
(OTHER INFO)

Boiling Pt:=100.C, 212.F
B.P. Text:APPROX RANGE 100 - 213
Vapor Pres:SEE OTHER INFO
Vapor Density:> AIR
VOC Grams/Liter:4.6
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:LIQUID, NO APPEARANCE OR ODOR SPECIFIED BY
MANUFACTURER
Percent Volatiles by Volume:66.2

Stability Indicator/Materials to Avoid:YES
NONE REASONABLE FORESEEABLE.
Hazardous Decomposition Products:CO, CO2, SMOKE, OXIDES OF HEAVY METALS
REPORTED IN (HEALTH HAZARDS) SECTION.

Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.

Toxicological Information:N/P. SIGNS AND SYMPTOMS OF
OVEREXPOSURE (CONT): THIS TO MAN IS UNKNOWN. CHROMOSOMAL CHANGES IN
THE CIRCULATING BLOOD OF EXPOSED WORKERS HAVE BEEN REPORTED. THE
SIGNIFICANCE OF THESE REPORTS IS UNCLEAR BECAUSE OF EXPOSURE TO
OTHER SUBSTANCES. XYLENE: RECURRENT OVEREXPOSURE MAY RESULT IN
LIVER AND KIDNEY INJURY. CAN BE ABSORBED THROUGH THE SKIN IN
HARMFUL AMOUNTS. CANADA CLASSIFIES XYLENE AS A DEVELOPMENTAL TOXIN
AS HIGH EXPOSURES TO XYLENES IN SOME ANIMAL STUDIES HAVE BEEN
REPORTED TO CAUSE HEALTH EFFECTS ON THE DEVELOPING FETUS / EMBRYO.
THESE EFFECTS WERE OFTEN AT LEVELS TOXIC TO THE ADULT ANIMAL. THE
(ECOLOGICAL INFO)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:N/P. TOXICOLOGICAL INFO (CONT): SIGNIFICANCE OF THESE
EFFECTS TO HUMANS IS NOT KNOWN. AROMATIC HYDROCARBON: LABORATORY
STUDIES WITH RATS HAVE SHOWN THAT PETROLEUM DISTILLATES CAN CAUSE
KIDNEY DAMAGE AND KIDNEY OR LIVER TUMORS. THESE EFFECTS WERE NOT
SEEN IN SIMILAR STUDIES WITH GUINEA PIGS, DOGS, OR MONKEYS. SEVERAL
STUDIES EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN A SIGNIFICANT
INCREASE OF KIDNEY DAMAGE OR AN INCREASE IN KIDNEY OR LIVER
TUMORS. NAPHTHALENE: RECURRENT OVEREXPOSURE MAY RESULT IN LIVER
AND KIDNEY INJURY. AROMATIC HYDROCARBON: LABORATORY STUDIES WITH
RATS HAVE SHOWN THAT PETROLEUM (TRANSPORT INFO)

Transport Information:N/P. ECOLOGICAL INFO (CONT): DISTILLATES
CAN CAUSE KIDNEY DAMAGE AND KIDNEY OR LIVER TUMORS. THESE EFFECTS
WERE NOT SEEN IN SIMILAR STUDIES WITH GUINEA PIGS, DOGS, OR
MONKEYS. SEVERAL STUDIES E VALUATING PETROLEUM WORKERS HAVE NOT
SHOWN A SIGNIFICANT INCREASE OF KIDNEY DAMAGE OR AN INCREASE IN
KIDNEY OR LIVER TUMORS. LEAD NAPHTHENATE: OVEREXPOSURE TO LEAD MAY
CAUSE ADVERSE EFFECTS TO THE BL OOD FORMING, NERVOUS, URINARY,
REPRODUCTIVE SYSTEMS INCLUDING EMBRYOTOXIC EFFECTS. SYMPTOMS MAY
INCLUDE LOSS OF APPETITE, ANEMIA, DISTURBANCE OF SLEEP AND FATIGUE.
SEE OSHA LEAD STANDARD 29 CFR 1910.1 025. FOR EXPOSURES LONGER
(SARA III)

SARA Title III Information:THE CHEMICALS LISTED ABOVE WITH PERCENTAGES
(TOLUENE; 1,2,4-TRIMETHYL BENZENE; XYLENE; CUMENE; NAPHTHALENE;
LEAD NAPHTHENATE) ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF THE EMERGENCY PLANNING AND RIGHT-TO-KNOW ACT OF
1986 AND OF 40 CFR 372. TRANSPORT INFO (CONT):THAN 8 HOURS
THE OSHA EXPOSURE LIMIT IS REDUCED BY THIS FORMULA: LIMIT (IN
UG/M3) = 400 / HOURS WORKED IN THE DAY . CAN BE ABSORBED THROUGH
THE SKIN IN HARMFUL AMOUNTS. VM&P NAPHTHA: LABORATORY STUDIES WITH
RATS HAVE SHOWN THAT PETROLEUM DISTILLATES CAN CAUSE KIDNEY DAMAGE
AND KIDNEY OR LIVER TUMORS. THESE EFFEC TS WERE NOT SEEN IN
(FEDERAL REGULATORY)
Federal Regulatory Information:OSHA NAME: FLAMMABLE LIQUID.
STATE REGULATORY (CONT): SIMILAR STUDIES WITH GUINEA PIGS, DOGS, OR
MONKEYS. SEVERAL STUDIES INVOLVING PETROLEUM WORKERS HAVE NOT SHOWN
A SIGNIFICANT INCREASE OF KI DNEY DAMAGE OR AN INCREASE IN KIDNEY
OR LIVER TUMORS. SKIN OR EYE CONTACT: MAY CAUSE IRRITATION OF THE
EYES. REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE IRRITATION. IN
CASE OF EYE CONTACT, FLUSH WIT H PLENTY OF WATER FOR AT LEAST 15
MINUTES, CALL A PHYSICIAN. FOR SKIN CONTACT, WASH WITH SOAP AND WA
TER. TOLUENE AND LEAD COMPOUNDS APPEAR ON THE NAVY OCCUPATIONAL
CHEMICAL REPRODUCTIVE HAZARDS LIST. (STATE REGULATORY)
State Regulatory Information:WARNING: THIS CHEMICAL (TOLUENE) IS KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. WARNING: THIS CHEMICAL (LEAD NAPHTHENATE) IS
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS
OR OTHER REPRODUCTIVE HARM. FEDERAL REGULATORY (CONT): SEEK
CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING
LATEST HEALTH HAZARD AND EXPOSURE INF ORMATION .